HYDROFORMYLATION OF ETHYLENE CATALYZED BY HOMOGENEOUS METAL CLUSTERS  

作　　者：Fu Hongxiang, Luo Yuzong , Zhang Shuwei, Ren Xu (Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China) 

出　　处：《分子催化》1989年第S1期88-93,共6页Journal of Molecular Catalysis(China)

基　　金：This work was supported by Science Foundation of Chinese Academy of Sciences

摘　　要：This paper deals with a study of hydroformylation of ethylene catalyzed by homoge-neous metal clusters.〔PhCH₂Me₃N〕〔FeCo₃（CO）₁₂〕and〔PhCH₂Me₃N〕〔RuCO₃（CO）₁₂〕show high catalytic activity for the hydroform ylation of ethylene compared with YCCo₃（CO）₉,CO₄（CO）₁₀（PPh）₂,Co₂（CO）₆（PBu₃）₂,and Fe₂（CO）₄（C₅H₅）₂.The reacton rate ofheteronuclear clusters is faster than that with homonuclear clusters.The effect of tempera-ture and pressure on hydroformylation of ethylene with〔PhCH₂Me₃〕〔FeCo₃（CO）₁₂〕ascatalyst was studied.The experimental results.show that the conversion of ethylene exceeds90% with a selectivity up to 95% at temperature 130℃ and pressure 3.9 MPa.When studiedwith high pressure in situ infrared spectroscopic method,PhCCo₃（CO）₉ was found to havehigher thermostability than 〔PhCH₂Me₃N〕〔FeCo₃（CO）₁₂〕.This paper deals with a study of hydroformylation of ethylene catalyzed by homogeneous metal clusters. [PhCH2Me3N][FeCo3(CO)12] and [PhCH2Me3N][RuCo3(CO)12] show high catalytic activity for the hydroformylation of ethylene compared with YCCo3 (CO)9, Co4(CO)10(PPh)2, Co2(CO)6(PBu3)2, and Fe2(CO)4(C5H5)2. Thereacton rate of heteronuclear clusters is faster than that with homonuclear clusters.The effect of temperature and pressure on hydroformylation of ethylene with [PhCH2Me3N] [FeCo3(CO) 12] as catalyst was studied. The experimental results, show that the conversion of cthylene exceeds 90% with a selectivity up to 95% at temperature 130℃ and pressure 3.9 MPa. When studied with high pressure in situ infrared spectroscopic method, PhCCo3(CO)9 was found to have higher thermostability than [PhCH2Me3N] [FeCo3 (CO) 12].

关 键 词：FECO faster SELECTIVITY tempera spectroscopic CRYSTALLINE CATALYZED silica deals CARBONYL 

分 类 号：O643[理学—物理化学]