聚乙烯醇/纳米羟基磷灰石复合水凝胶溶胀机制和启动摩擦性能研究  

Research on the Swelling Mechanism and Friction Properties of Start-up for Polyvinyl Alcohol/Hydroxylapatite Composite Hydrogel

作　　者：沈艳秋[1] 张德坤[2] 钱善华[2] 葛世荣[2] 

机构地区：[1]金陵科技学院龙蟠学院,江苏南京211169 [2]中国矿业大学材料科学与工程学院,江苏徐州221116

出　　处：《润滑与密封》2009年第5期42-46,共5页Lubrication Engineering

基　　金：国家自然科学基金项目(50535050;50405042);教育部新世纪优秀人才支持计划项目(NCET-06-0479);江苏省自然科学基金项目(BK2005403;BK2005019)

摘　　要：选用高分子聚乙烯醇(PVA)和纳米羟基磷灰石(HA)为原料,采用反复冷冻-解冻法制备PVA/HA复合水凝胶。利用光学显微镜考察PVA/HA复合水凝胶的溶胀性能,用精密位移传感器对PVA/HA复合水凝胶的接触变形特性进行测量,在小牛血清稀释液润滑条件下进行PVA/HA复合水凝胶的往复式摩擦试验,考察冷冻-解冻次数和接触时间对PVA/HA复合水凝胶启动摩擦性能的影响。结果表明:PVA/HA复合水凝胶是一种交联网状微观结构,溶胀性能优异;随着冷冻-解冻次数的增加,PVA/HA复合水凝胶交联度增大,网状结构趋于完善,其接触变形越小,恢复变形所需的时间越短;PVA/HA复合水凝胶在滑动过程中的法向位移量和启动摩擦因数随反复冷冻-解冻次数的增加而减小,随接触时间的延长而增大。The polyvinyl alcohoL/hydroxylapatite （PVA/HA） composite hydrogel was prepared by reiterative freezing- thawing method using the raw materials of maeromolecular PVA and nano-HA. The swelling properties were investigated by using the optical microscope. The contact deformation of PVA/HA composite hydrogel was measured using an exact dis- placement sensor. The influence of freezing-thawing times and contact time on the friction properties of start-up of PVA./ HA composite hydrogel in the diluted bovine serum solution was studied by reciprocating sliding tests. The results show that the PVA/HA composite hydrogel has a cross-linkage and netlike construction, which has excellent swelling property. The cross-linking degree of the PVA/HA composite hydrogel increases and the network structure tends to perfect with the in- creasing of freezing-thawing cycles. The contact deformation and the restoration time of deformation are inversely propor- tional to the freezing-thawing cycles. The normal displacement and the start-up friction coefficient of PVAZHA composite hydrogel decrease with the increasing of the freezing-thawing times, and they increase with the increasing of contact time.

关 键 词：聚乙烯醇 羟基磷灰石 复合水凝胶 溶胀机制 启动摩擦性能 

分 类 号：R318.08[医药卫生—生物医学工程]