截流法和温度跃升法测定Fe^(3+)-CNS^-体系的反应速率常数  

DETERMINATION OF RATE CONSTANT OF Fe^(3+)-CNS-BY STOPPED-FLOW AND TEMPERATURE-JUMP METHODS

作　　者：王元芳[1] 秦金妹[1] 蔡显鄂[1] 

机构地区：[1]复旦大学化学系

出　　处：《复旦学报（自然科学版）》1989年第1期19-23,共5页Journal of Fudan University：Natural Science

摘　　要：用截流法和温度跃升法测定了Fe^(3+)-CNS^-体系第一步络合反应的表观速率常数k_1和反应速率常数后k_1,并对第二步络合反应作了讨论。Apparent rate constant k_f and rate constant k_1 of the first step of complexationbetween Fe^(3+) and CNS^- have been determined by using of stopped-flow andtemperature-jump methods. The second step of complexation has also beenpediscussed.

关 键 词：硫氰酸盐 反应速率 截流法 

分 类 号：O623.765[理学—有机化学]