聚苯乙烯基硫代磺酸钾树脂的合成及其与卤代烃的反应  

THE SYNTHESIS OF POTASSIUM POLYSTYRYL-THIOSULFONATE RESIN AND ITS REACTION WITH HALOGENATED HYDROCARBONS

作　　者：吴萼[1] 刘秀芬[1] 曹海峰[1] CarlsonRM 

机构地区：[1]中国科学院生态环境研究中心,北京100085 [2]DepartmentofChemistry,UniversityofMinnesota,

出　　处：《环境化学》1998年第3期237-242,共6页Environmental Chemistry

基　　金：国家自然科学基金资助项目(批准号:29477278)

摘　　要：由聚苯乙烯基磺酰氯树脂与硫化氢钾反应制备聚苯乙烯基硫代磺酸钾树脂（Ⅰ）,树脂Ⅰ与亲电的卤代烃反应,生成聚苯乙烯基硫代磺酸酯树脂（Ⅱ）,树脂Ⅱ经过乙硫醇处理,使卤代烃结构部分以不对称二硫醚的形式游离下来,用GC/MS对其结构进行鉴定,从不对称二硫醚的结构可推导出原卤代烃的结构,所制备的聚苯乙烯基硫代磺酸钾树脂的转化效率为1.11mmol·g^(-1)。Potassium polystyrylthiosulfonate resin (I) was prepared from the reaction of polystyrylsulfonyl chloride with KHS. Resin I reacted with electrophilic halogenated hydro-carbons to produce polystyrylthiosulfonic esters resin (Ⅱ). The resin Ⅱ were treated with excess mercaptan and the structure parts of the helogenated hydrocarbons were dissociated from the resin as unsymmetrical disulfides which were determined by GC-MS. The structure of the original halogenated hydrocarbons could be deduced from that of unsymmetrical disulfide obtained. The capacity of the potassium polystyrylthiosulfonate resin prepared is 1.11 mmol·g-1.

关 键 词：聚苯乙烯 硫代磺酸钾 卤代烃 污染物 

分 类 号：X132[环境科学与工程—环境科学]