恶唑烷类化合物水解过程中的线性关系  

THE LINEAR RELATIONSHIPS OF OXAZOLIDINE COMPOUNDS IN THEIR HYDROLYSIS

作　　者：李存保[1,2] 王美玲 马翼寅 张翠荣[1,2] 陈其秀 陈宝皎[1,2] 

机构地区：[1]内蒙古医学院基础部化学教研室 [2]呼和浩特卫生学校化学教研室

出　　处：《内蒙古师范大学学报（自然科学汉文版）》1998年第2期115-117,共3页Journal of Inner Mongolia Normal University(Natural Science Edition)

摘　　要：测定了２３种恶唑烷类化合物在水溶液中的水解速度常数Ｋｏｂｓ、离解常数Ｋａ和在有机溶剂硝基苯中的半中和点电位Ｅ１／２．并对其两两之间的线性关系进行了探讨．发现不但Ｋｏｂｓ、ＰＫａ和Ｅ１／２相互之间均具有线性关系。In this thesis the kinetics hydrolysis rate constants Kobs of 23 kinds of the oxazolidine compounds,their dissocition constants Ka in aqueous solution and the helfneutralization potentials E1/2 in organic solvent were determined,and their linear relationship between each other was inquired into.

关 键 词：水解速度常数 恶唑烷 离解常数 线性关系 

分 类 号：O626.2[理学—有机化学]