联苯乙酮缩氨基硫脲过渡金属配合物的合成及其对水稻白叶枯病菌的杀菌活性研究  

SYNTHESIS OF TRANSITION METAL COMPLEXES OF 4ACETYLBIPHENYLTHIOSEMICARBAZONE AND THEIR ACTIVITIES AGAINSTXANTHOMONAS ORYZA

作　　者：毕思玮[1,2] 李桂芝[1,2] 刘树祥[1,2] 

机构地区：[1]曲阜师范大学化学系 [2]曲阜师范大学生物系

出　　处：《无机化学学报》1998年第2期153-156,共4页Chinese Journal of Inorganic Chemistry

基　　金：山东省教委资助

摘　　要：合成了联苯乙酮缩氨基硫脲及其铜（Ⅱ）、锌（Ⅱ）、钴（Ⅱ）、镍（Ⅱ）的配合物，通过元素分析、摩尔电导、红外光谱、电子光谱以及磁化率等进行了表征，用浓度稀释法研究了它们对水稻白叶枯病菌的杀菌活性。试验发现，铜（Ⅱ）配合物对该菌具有良好的杀菌活性。The complexes of 4acetylbiphenyl thiosemicarbazone with Cu(Ⅱ), Zn(Ⅱ), Ni(Ⅱ), Co(Ⅱ) were synthesized and characterized by elemental analysis, molar conductance, infrared spectra, electronic spectra and magnetic susceptibility. The bactericidal activities of the ligand and the complexes against xanthomonas oryza were examined by concentration dilution method. Results showed that the ligand and the complexes of Cu(Ⅱ) and Zn(Ⅱ) have bactericidal activitits, with the Cu(Ⅱ) complex higher activity.

关 键 词：配合物 杀菌活性 联苯乙酮 缩氨基硫脲 

分 类 号：TQ455.4[化学工程—农药化工]