2,3,5,6-四氟对二甲苯侧链新型溴化物的合成  

Synthesis of Novel Side Chain Brominated 2,3,5,6-Tetrafluoroxylenes

作　　者：谢普会[1] 郭丰启[2] 金秋[1] 谢黎霞[1] 

机构地区：[1]河南农业大学理学院,郑州450002 [2]郑州大学化学系,郑州450001

出　　处：《河南科学》2009年第7期790-792,共3页Henan Science

基　　金：教育部留学回国人员科研启动基金(教外司留[2008]890号);河南农业大学博士基金(30700228)

摘　　要：研究合成了3个2,3,5,6-四氟甲苯的侧链新型溴化物,并对它们的结构进行了质谱,1HNMR,19FNMR,元素分析等表征.这些化合物是合成四氟苯化合物、四氟苯聚合物、氟化对二亚甲基苯类二聚物的重要中间体.Three novel side chain brominated 2, 3,5,6-tetrafluorobenzenes were prepared. The structures of the products were primarily identified by HRMS, 1H NMR, 19F NMR, and elemental analysis. These compounds were promising intermediates for fluorinated [2.2] paracyclophanes and fluoropolymers.

关 键 词：侧链溴化 2 3 5 6-四氟甲苯 前体 

分 类 号：O625.34[理学—有机化学]