气相色谱-质谱联用对纺织品中16种含氯酚及邻苯基苯酚、β-萘酚残留量的测定  

Determination of 16 Chlorophenols,o-Phenyphenol and β-Naphthol in Textiles by GC-MS

作　　者：樊苑牧[1] 贺小雨[1] 俞雪钧[1] 顾晓俊[1] 陈树兵[1] 湛嘉[1] 

机构地区：[1]宁波出入境检验检疫局技术中心,浙江宁波315012

出　　处：《分析测试学报》2009年第7期794-798,803,共6页Journal of Instrumental Analysis

基　　金：宁波出入境检验检疫局课题资助项目(甬K17-2005项目)

摘　　要：建立了气相色谱-质谱（GC—Ms）测定纺织品中16种含氯酚及邻苯基苯酚、β-萘酚残留量的方法。样品经甲醇超声提取、浓缩后，用0．1mol／L硼砂溶液溶解，再经乙酸酐乙酰化后正己烷提取，用GC—MS测定，内标法定量。在0．025—1．0mg／L范围内，方法的线性关系良好，相关系数为0．9993—0．9999，添加回收率为83％-112％，相对标准偏差为0．26％-8．82％。该方法简便、快速、灵敏度高，完全可满足进出口纺织品中16种含氯酚及邻苯基苯酚、β-萘酚残留量检测的要求。A GC -MS method was developed for the determination of 16 chlorophenols, o-phenyphenol and β-naphthol in textiles. The sample was extracted with methanol in ultrasonic bath. The extract was concentrated and redissolved in 0. 1 mol/L borax solution, then was derivatized by acetic anhydride and extracted by hexane. The target of compounds were analyzed by GC - MS with internal standard method. The result indicated that the calibration curves showed good linear relationships between the peak area and concentration in the range of 0. 05 - 1.0 mg/L for o-phenyphenol（OPP） and ,β-naphthol（ B - N）, and 0. 025 - 1.0 mg/L for the rest of analytes. The correlation coefficients were in the range of 0. 999 3 -0. 999 9. The average recoveries of 16 chlorophenols, o-phenyphenol and β-naphthol from the eontton sample spiked at three concentration levels of 0. 05, 0. 1,0. 5 mg/kg ranged from 83% to 112% with relative standard deviations of 0. 26% - 8.82% . The method was simple, rapid and sensitive, and was suitable for the determination of 16 chlorophenols, o-pheny- phenol and β-naphthol in the import and export of textiles.

关 键 词：纺织品 氯酚 邻苯基苯酚 Β-萘酚 气相色谱-质谱 

分 类 号：O657.63[理学—分析化学] O625.3[理学—化学]