镍配合物[Ni(C_(10)H_8N_2)(C_7H_4O_5N_3)(H_2O)]·ClO_4的合成及晶体结构  

Synthesis and crystal structure of [Ni(C_(10)H_8N_2)(C_7H_4O_5N_3)(H_2O)]·ClO_4

作　　者：罗志刚[1] 胡小芳[1] 易绣光[1] 钟凡[1] 应少明[1] 王琪[1] 

机构地区：[1]井冈山大学,江西吉安343009

出　　处：《化学研究与应用》2009年第8期1124-1128,共5页Chemical Research and Application

基　　金：江西省教育厅科技项目资助(GJJ09332)

摘　　要：The title complex[Ni(C10H8N2)(C7H4O5N3)(H2O)]ClO4 was synthesized by Taurine 2-hydroxy-3,5-dinitrobenzaldehyde schiff base,2,2’-bipyridine and nickel(II) perchloride in ethanol solution,and the crystal structure was determined by X-ray diffraction method.The crystal belongs to Monoclinic system,space group P21/c,with cell parameters:a=7.4481(3),b=24.1832(9),c=11.6691(4),β=98.021(2)°,V=2081.26(13)3.The nickel(II) atom is coordinated by two N atoms from one 2,2’-bipyridine molecule,one O atom and one N atom from a 2-hydroxy-3,5-dinitrobenzaldehyde imine molecule,one O atom from a coordinated water,resulting in a square-pyramid geometry.The packing diagram shows that a three-dimensional network is formed via intermolecular attractive force.The rifle complex [ Ni （ C10 H8 N2 ） （ C7 H4 O5 N3 ） （ H2O ） ] AClO4 was synthesized by Taurine 2-hydroxy-3, 5- dinitrobenzaldehyde schiff base , 2,2＇-bipyridine and nickel （Ⅱ） perchloride in ethanol solution, and the crystal structure was determined by X-ray diffraction method. The crystal belongs to Moneclinic system, space group P21/c, with cell parameters：a = 7. 4481（3） ,b =24. 1832（9） ,c = 11.6691（4）A,β=98.021（2）°,V=2081.26（13）A^3.The nickel （II） atom is coordinated by two N atoms from one 2,2＇ -bipyridine molecule,one O atom and one N atom from a 2-hydroxy-3,5-dinitrobenzaldehyde imine molecule , one O atom from a coordinated water,resulting in a square-pyramid geometry. The packing diagram shows that a three-dimensional network is formed via intermolecular attractive force.

关 键 词：合成 晶体结构 镍配合物 

分 类 号：O614.121[理学—无机化学]