O,O-二乙基硫代磷酰氯生产残液的成分解析  

Composition of Distilling residue of o,o-Diethylthionophosphoric Acid Chloride

作　　者：朱国念[1] 赵金浩[1] 程敬丽[1] 戴金贵 阳艺 徐振元[3] 

机构地区：[1]浙江大学农药与环境毒理研究所,杭州310029 [2]浙江新农化工股份有限公司,浙江台州317300 [3]浙江工业大学催化加氢研究中心绿色化学合成技术国家重点实验室培育基地,杭州310014

出　　处：《农药》2009年第8期576-578,共3页Agrochemicals

摘　　要：通过气质联用方法,对O,O-二乙基硫代磷酰氯(1#,乙基氯化物)蒸馏残液的杂质结构与形成机理进行研究。经定性分析发现:1#的残液中主要包括氯乙烷等A～L12种杂质。从其结构上分析,如果要提高1#的总收率,则可在生产过程中控制氯气的用量、控制五硫化二磷的质量、降低蒸馏温度、提高真空度。The impurities in the distilling residue of O,O-diethylthionophosphoric acid chloride （1^#） and their forming mechanism were resolved by GC-MS to found for their controling, industrial reaction condition optimizing, yield increasing of 1^# and environmental disposing. As a result, twelve impurities A-L such as chloroethane were found in the residue. According to the structure of these impurities, it is possible to improve the yield of 1^# by controling both the quantity of chlorine and the quality of phosphorus pentasulfide, decreasing the distilling temperature or increasing the vacuum in the process of manufacturing 1^#.

关 键 词：气质联用 乙基氯化物 蒸馏残液 杂质结构解析 

分 类 号：TQ450.7[化学工程—农药化工]