Ph_2C(OH)CH=CHSnAr_3的卤化物的合成、表征和性质  

Synthesis, Properties and Structure of the Halides of (Z)-3-triarylstannyl-1,1-diphenyl-2-propenyl-1-ol

作　　者：朱东升[1] 戴慧聪[1] 单希林[1] 傅芳信[1] 潘华德[1] 

机构地区：[1]东北师范大学化学系,长春130024

出　　处：《有机化学》1998年第5期447-451,共5页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金

摘　　要：首镒以非碳环醇－３－三芳基锡基－１，１－二苯基－２－丙烯基－１－醇「Ｐｈ２Ｃ（ＯＨ）ＣＨ＝ＣＨＳｎＡｒ３」和卤素或拟卤素发生取代反应得到卤化物，并以此合成了氢氧化物，氧化物和配合物。通过元素分析，ＩＲ和＾１Ｈ ＮＭＲ等对上述１７种新化合物的结构进行表征，并提出了卤化物的性质。the reaction of the compound (Z) - 3 - triaiylstannyl -1,1 - diphenyl - 2 - propenyl - 1 -ol with ICl,Br2,I2 formed organotin halides,which reacted with KOH to form organotin oxide or hydroxide.The complexes were obtained by the organotin halides with three ligandrs (2,2' - bipyridyl, 1,10 - phenanthroline, 8 - hydroxyquinoline). The seventeen new compounds were characterized by means of elemental analysis, IR and 1H NMR.Studied on the properties of the halides.

关 键 词：有机锡化合物 卤化物 配合物 合成 抗癌活性 

分 类 号：O627.42[理学—有机化学] R979.1[理学—化学]