寡聚酸合铁(Ⅲ)制备工艺的研究  

Study on Preparation of Iron (Ⅲ) Glucose Oligosaccharide Acids

作　　者：王士奎[1] 刘卫萍[1] 张志民[1] 孟宪金[1] 

机构地区：[1]农业部规划设计研究院,北京100125

出　　处：《广州化工》2009年第8期3-5,共3页GuangZhou Chemical Industry

基　　金：国家863计划计划引导项目(2005AA001240)

摘　　要：以寡聚酸和三氯化铁为原料,研究了不同的反应体系pH值和配位比对寡聚酸合铁(Ⅲ)合成及其水解稳定性的影响,并且用红外光谱分析对寡聚酸合铁(Ⅲ)的结构进行了表征。试验结果表明:经过单因素试验,确定出反应的最佳pH值为6,最佳配位比为:寡聚酸/铁=1:16。将纯化后的产品做红外光谱分析,并和纯品寡聚酸的红外光谱做了比较,证明寡聚酸合铁(Ⅲ)成螯合状态。Iron （Ⅲ） glucose oligosaccharide acids was prepared by glucose oligosaccharide acids and ferric trichloride in water solutions. The effects of pH and molar ratios on preparation and rehydration of iron （ Ⅲ ） glucose oligosac- charide acids were firstly studied. By single factor experiments, the synthesis technology was confirmed. The optimal reaction condition was as follow： pH was 6, the molar ratio of glucose oligosaccharide acids to iron was 16 ： 1. The infrared spectrometry of iron （ Ⅲ ） glucose oligosaccharide acids showed that it existed with a chelating compound structure.

关 键 词：寡聚酸合铁(Ⅲ) PH 配位比 水解稳定性 红外光谱 

分 类 号：TQ645.6[化学工程—精细化工] O614.811[理学—无机化学]