有机酸无机离子对土壤镉铅解吸特性的影响  

Effect of organic acid and inorganic ion on desorption character of cadmium and lead

作　　者：陈苏[1,2,4] 孙丽娜[1,2,4] 晁雷[3,4] 牛之欣[1] 张鸿龄[1] 孙铁珩[1,4] 

机构地区：[1]沈阳大学污染环境的生态修复与资源化技术实验室,辽宁沈阳110044 [2]污染环境修复与生态健康教育部重点实验室,浙江大学环境与资源学院,浙江杭州310029 [3]辽宁省环境科学研究院,沈阳110031 [4]中国科学院沈阳应用生态研究所,辽宁沈阳110016

出　　处：《辽宁工程技术大学学报（自然科学版）》2009年第5期831-834,共4页Journal of Liaoning Technical University (Natural Science)

基　　金：国家高技术研究发展计划(863)基金资助项目(2007AA06A405);国家水体污染控制与治理科技重大专项基金资助项目(2008ZX07208-003);辽宁省优秀人才支持计划基金资助项目(20092244);污染环境修复与生态健康教育部重点实验室开放基金(EREH0713);中国科学院陆地生态过程重点实验室开放基金资助项目资助

摘　　要：为深入了解草甸棕壤中镉、铅的解吸行为,采用一次平衡法探讨有机酸、无机离子对镉、铅解吸特性的影响。结果表明,柠檬酸、草酸、组氨酸摩尔浓度较低时,有机配位体抑制镉的释放,而有机酸摩尔浓度较高时(>2 mmol·L-1)将明显促进镉的释放。柠檬酸、草酸、组氨酸对Pb的解吸率随有机酸摩尔浓度提高(0-20 mmol·L-1)而增大,对Cd、Pb浸提能力的大小关系为:柠檬酸﹥草酸﹥组氨酸。随解吸液中无机离子(C1-、SO42-、F-)摩尔浓度的增大,镉、铅的解吸率亦随之提高。无机离子对解吸土壤中Cd的影响力顺序是:C1->SO42->F-;对解吸土壤中Pb的影响力顺序是:SO42->C1->F-。In order to understand the desorption behavior of Cd and Pb in meadow brown soil,a batch experiment was conducted to investigate the effect of organic acid and inorganic ion on the desorption characteristics of Cd and Pb.Results showed that when the concentration of organic acids（citric acid,oxalic acid and histidine） in desorption solution was relatively low,the presence of organic ligands inhibited Cd desorption.When organic acids’ concentration was higher（greater than 2 mmol/L）,the presence of organic acids obviously accelerated Cd desorption.Pb desorption rate in three organic acids solutions（citric acid,oxalic acid and histidine） increased with the concentration increase of organic acids（0-20 mmol.L-1）.The desorption capacities for Cd and Pb were ranked as follows： citric acid oxalic acid histidine.With the concentration increase of inorganic ions（C1-、SO42-、F-）,the desorption rate of Cd and Pb also increased.The influences of inorganic ions on Cd were ranked as follows： C1- SO42- F-.The influences of inorganic ions on Pb were ranked as follows： SO42- C1- F-.

关 键 词：镉 铅 有机酸 无机离子 解吸 

分 类 号：S153[农业科学—土壤学]