硝酸氧化乙醛制乙二醛新工艺  

New Process of Making Biformyl with EthanalOxidated by Nitric Acid

作　　者：陈坤[1] 成忠兴[1] 徐雄立 

机构地区：[1]湖北工学院化学工程系

出　　处：《湖北工学院学报》1998年第2期48-52,共5页

摘　　要：研究了以高碳氧化叔胺作为硝酸氧化乙醛制乙二醛的催化剂，保护醛基，提高硝酸氧化乙醛甲基的选择性；并探讨了反应温度、催化剂用量及物料配比对乙二醛收率的影响，获得了较适宜的工艺条件．The increase of the selectivity of oxidating methyl group is discussed. Highcarbon tertiary amine was used as catalyst in the reaction with ethanal oxidated by nitric acid to protect aldehyde group. The effect of temperature, catalyst usuage and formula of materials on the yield of biformal is also investigated.And an appropriate process condition is thus obtained.

关 键 词：乙二醛 硝酸 氧化 乙醛 制备 工艺 

分 类 号：TQ224.14[化学工程—有机化工]