基团电负性与含氮含硫有机物的键裂能  

The Group Electronegativity and Bond Dissociation Energies of Organic Compounds Containing Nitrogen or Sulfur

作　　者：钮银峰[1] 张秀利[1] 

机构地区：[1]河北科技大学基础课部

出　　处：《河北师范大学学报（自然科学版）》1998年第4期538-541,共4页Journal of Hebei Normal University：Natural Science

摘　　要：建立了用基团电负性计算含氮含硫有机物的键裂能的简单方法．利用此方法计算出２２个含氮含硫烷基衍生物的键裂能，其平均偏差为３．７０ｋＪｍｏｌ－１．A simple method has been built up for calculating the bond dissociation energies of organic compounds containing nitrogen or sulfur by use of group electronegativity.We have calculated bonds dissociation energies for 22 alkyl derivatives containing nitrogen or sulfur,their average derivation is 3.70kJ·mol -1

关 键 词：基团 电负性 含氮 含硫有机物 键裂能 

分 类 号：O621.12[理学—有机化学] O622.6[理学—化学]