甲酰基甲酸缩氨基硫脲和1,10-菲啰啉的过渡金属配合物的合成、表征及杀菌活性  

Synthesis, characterization and sterilizing activity of bivalent transition metal ion ternary complexes derived from formoyl formic acid thiosemicarbazone and 1,10 phenanthroline

作　　者：刘树祥[1] 高恩庆[1] 田君濂[1] 毕思玮[1] 张建民[2] 李桂芝[2] 

机构地区：[1]曲阜师范大学化学系 [2]曲阜师范大学生物系

出　　处：《化学试剂》1998年第6期327-330,共4页Chemical Reagents

基　　金：山东省教委资助课题

摘　　要：合成了组成为ＭＬＢ·ｎＨ２Ｏ［Ｍ＝Ｍｎ（Ⅱ）、Ｃｕ（Ⅱ）、Ｚｎ（Ⅱ）和Ｃｄ（Ⅱ），ｎ＝１；Ｍ＝Ｎｉ（Ⅱ），ｎ＝２；Ｌ＝甲酰基甲酸缩氨基硫脲；Ｂ＝１，１０－菲啉］的５种三元配合物。测定了其元素组成、摩尔电导率和磁化率；用电子光谱和红外光谱进行表征，提出了它们的结构。研究了配体甲酰基甲酸缩氨基硫脲及其配合物的杀菌活性。The bivalent transition metal ion ternary complexes derived from formoyl formic acid thiosemicarbazone (H 2FFTSC) and 1,10 phenanthroline (1,10 Phen) have been prepared and characterized by physical and chemical methods. The studies of electronic and IR spectra and magnetic moment value suggest an octahedral geometry for all the ternary complexes, where low molar conductance values are in accord with their non electrolytic nature. The sterilizing activities of the H 2FFTSC and its complexes were studied.

关 键 词：过渡金属 配合物 缩氨基硫脲 菲罗啉 杀菌活性 

分 类 号：O614[理学—无机化学] O641.4[理学—化学]