9-蒽甲胺的合成  

The Synthesis of 9-Aminomethylanthracene

作　　者：王奇观[1] 曹永军[2] 王素敏[1] 

机构地区：[1]西安工业大学材料与化工学院,陕西西安710032 [2]驻马店教育学院,河南驻马店463000

出　　处：《精细化工中间体》2010年第2期61-63,共3页Fine Chemical Intermediates

摘　　要：以9-蒽甲醇为原料,通过溴化、叠氮基亲核取代、催化氢化3步反应制备了9-蒽甲胺,总收率达60%。利用1HNMR、质谱、元素分析对产物的组成和结构进行了确认和鉴定。研究结果表明,以Pd/C为催化剂,催化氢化在常温常压下能够快速进行,40min就可完全反应。9-Aminomethylanthracene is a versatile intermediate in organic synthesis. In this paper it was prepared from 9-anthylmethanol in three steps, including bromination, nucleophilic replacement with azid and Pd/C catalyzed hydrogenation, in 60% overall yield. The hydrogenation finished within 40 min at room temperature and under atmospheric pressure. The structure of the target compound was characterized with ^1H NMR, ESI-MS and elemental analysis.

关 键 词：9-蒽甲胺 9-蒽甲醇 合成 

分 类 号：O621.25[理学—有机化学]