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作 者:雷园园[1] 傅德君[1] 李金钗 郭怀喜 叶明生 范湘军
机构地区:[1]武汉大学理学院加速器实验室
出 处:《太阳能学报》1999年第1期49-54,共6页Acta Energiae Solaris Sinica
基 金:国家自然科学基金
摘 要:用离化团簇束(ICB)沉积法制备了C60薄膜。XRD测试表明,膜呈多晶结构;原位电阻测试表明,膜的室温电阻率超过103Ωcm,具有负的电阻温度系数。用80keVp+,BBr3+,Ar+和He+对C60膜作剂量范围为0—1016cm-2的离子注入,C60膜的电阻率随注入剂量的增加而下降,p+注入使膜呈n型电导,离子与C60团簇的相互作用导致C60分裂,并使膜表面非晶化。在沉积过程中溅射掺Al得到p型C60膜。C60/Si样品具有明显的异质结特性,光照对结特性有明显响应。C 60 films are prepared by means of ionized cluster beam(ICB) deposition,X ray diffraction(XRD) measurement showed that the C 60 films are of polycrystalline.The films show negative resistance temperature coefficients,and their room temperature resistivity is greater than 10 2 Ωcm.The films were implanted with 80keV phosphorus,BBr 3,Ar,and He ions,under doses ranging up to 10 16 cm -2 The resistivity of the implanted films decreases with increasing doses n type electrical conduction was observed for phosphorus implanted C 60 films.The interaction of impinging ions with C 60 clusters was found to force the C 60 molecules to disintegrate and the films to amorphize.p type conduction was observed for the C 60 films doped with aluminum by simultaneously sputtering aluminum during deposition.C 60 /Si structures show heterojunction characteristics and the characteristics is influenciable by light illumination.The photoelectrical properties of the films were found improved by doping of aluminum.
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