强酸型树脂催化L-苯丙氨酸甲酯化研究  

STUDY ON METHYL ESTERIFICATION OF L PHENYLALANINE CATALYZED BY STRONG ACID TYPE RESIN

作　　者：樊可可[1] 欧阳平凯[1] 吴锡军 

机构地区：[1]南京化工大学生物工程与科学系

出　　处：《化学研究与应用》1999年第1期83-85,共3页Chemical Research and Application

摘　　要：１前言对酯化反应所用催化剂，一般使用强酸，如浓硫酸、浓盐酸等。另外，许多Ｌｅｗｉｓ酸，如三氟化硼、三氯化铝、氯化锌和硅胶等也能促进羰酸提供质子［１］。近年来的研究发现，强酸型阳离子交换树脂亦可用于催化某些酯化过程［２］。Ｌ－苯丙氨酸的甲酯化反应，传统...The catalytic activity of strong acid type ion exchange resin in esterification of L phenylalanine by methanol was investigated.An optimum technological condition was found as follows, under methanol/L phenylalanine mole ratio 1∶1,catalyst amount 45g/L,temperature 80～85℃ and reaction time 8h.Compared with traditional technology it was an ideal method for producting L phenylalanine methyl ester because of its good yield,low cost and simplicity of operation.

关 键 词：强酸型树脂 催化剂 酯化 L-苯丙氨酸甲酯 

分 类 号：TQ225.241[化学工程—有机化工] O643.36[理学—物理化学]