无溶剂条件下锰(Ⅲ)-席夫碱配合物催化过氧化氢氧化醇(英文)  

Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(Ⅲ) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant

作　　者：Hamid GOLCHOUBIAN Seyyed Ebrahim BABAEI 

机构地区：[1]Department of Chemistry,University of Mazandaran [2]Departmant of Chemistry,Islamic Azad University-Ghaemshahr Branch

出　　处：《催化学报》2010年第6期615-618,共4页

基　　金：Supported by the Islamic Azad University-Ghaemshahr branch of the Islamic Republic of Iran

摘　　要：Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(Ⅲ) Schiff-base complex as a catalyst under solvent-free conditions.The oxidation of alcohols occurred at 50℃ to give the corresponding ketones or carboxylic acids with a yield higher than 60%.Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn（Ⅲ） Schiff-base complex as a catalyst under solvent-free conditions.The oxidation of alcohols occurred at 50℃ to give the corresponding ketones or carboxylic acids with a yield higher than 60%.

关 键 词：酒精 氧化 氢过氧化物 Schiff 底建筑群 Mn (III ) 建筑群 酉同类 

分 类 号：O643.32[理学—物理化学]