含腈基的电活性聚芳醚酮的合成与表征  

Synthesis and Characterization of New Electroactive Polyaryletherketone Containing Benzonitrile Structure

作　　者：姚雷[1] 晁单明[1] 刘新才[1] 李智亮[1] 王策[1] 

机构地区：[1]吉林大学麦克德尔米德实验室,长春130012

出　　处：《高等学校化学学报》2010年第6期1078-1080,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:50873045);国家"八六三"计划项目(批准号:2007AA03Z324)资助

摘　　要：A new electroactive polyaryletherketone containing benzonitrile(EPEEK-CN) was synthesized from 2,6-difluorobenzonitrile,p-benzenediol and difluoromonomer containing phenyl-capped aniline tetramer segment,via ternary polycondensation.The obtained EPEEK-CN shows certain extent solubility in organic solvents,and its film casted from DMAc solution exhibits interesting electrical,mechanical and dielectric properties.A new electroactive polyaryletherketone containing benzonitrile（EPEEK-CN） was synthesized from 2,6-difluorobenzonitrile,p-benzenediol and difluoromonomer containing phenyl-capped aniline tetramer segment,via ternary polycondensation.The obtained EPEEK-CN shows certain extent solubility in organic solvents,and its film casted from DMAc solution exhibits interesting electrical,mechanical and dielectric properties.

关 键 词：电活性 氧化偶联 有机可溶性 高介电常数 

分 类 号：O631[理学—高分子化学]