Ball Milling Synthesis and Property of Nd_(0.7)Sr_(0.3)MnO_3 Manganites  

作　　者：Shunsheng Chen Changping Yang Lingfang Xu Shaolong Tang 

机构地区：[1]The Provincial Key Laboratory of Piezoelectric Ceramics Materials and Apparatus, Faculty of Physics and Electronic Technology, Hubei University, Wuhan 430062, China [2]Department of Physics, Nanjing University, Nanjing 210093, China

出　　处：《Journal of Materials Science & Technology》2010年第8期721-724,共4页材料科学技术（英文版）

基　　金：the National Natural Science Foundation of China (Grant No.10774040) and the joint Chinese-Russian Project for their financial supports

摘　　要：Strontium doped perovskite-type Nd0.7Sr0.3MnO3 ceramics were synthesized completely by high-energy ball milling raw oxides of Nd2O3, SrCO3 and MnO2. The optimal ball milling time and mass ratio of milling balls to raw materials are 4 h and 10：1, respectively. The grain size of as-milled Nd0.7Sr0.3MnO3 ceramics ranges from 51 to 93 nm, and the fine particles contain two phases of crystalline phase and amorphous phase. For the Nd0.7r0.3MnO3 synthesized by ball milling and sequent heat treatment, a remarkable colossal electroresistance （CER） effect is observed and the CER ratio reaches 900% at Curie temperature Tc when the load voltage increases from 0.1 to 0.8 V.Strontium doped perovskite-type Nd0.7Sr0.3MnO3 ceramics were synthesized completely by high-energy ball milling raw oxides of Nd2O3, SrCO3 and MnO2. The optimal ball milling time and mass ratio of milling balls to raw materials are 4 h and 10：1, respectively. The grain size of as-milled Nd0.7Sr0.3MnO3 ceramics ranges from 51 to 93 nm, and the fine particles contain two phases of crystalline phase and amorphous phase. For the Nd0.7r0.3MnO3 synthesized by ball milling and sequent heat treatment, a remarkable colossal electroresistance （CER） effect is observed and the CER ratio reaches 900% at Curie temperature Tc when the load voltage increases from 0.1 to 0.8 V.

关 键 词：High-energy ball milling Perovskite structure Colossal electroresistance （CER） Microstructure defect 

分 类 号：TQ920.5[轻工技术与工程—发酵工程] TF125.3[冶金工程—粉末冶金]