Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=Zn~ⅡI , Co~Ⅱ , Ni~Ⅱ)  

作　　者：ZHANG Yong-feng JIA Yan-yan NIE Hai-liang YAN Xing-juan WANG Li HUANG Ru-dan 

机构地区：[1]Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China

出　　处：《Chemical Research in Chinese Universities》2010年第5期683-686,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(Nos.20771013, 20476011 and 20371007)

摘　　要：Three new Keggin polyoxometalates, [Zn（phen）3]2[SiW12O40]＇5H2O（1）, [Co（phen）3]2[SiW12O40]（2） and [Ni（phen）3]2[SiW12O40].2H2O（3）（phen=1,10＇-phenanthroline） have been hydrothermally synthesized and characterized by elemental analysis, IR, crystal X-ray diffraction, thermogravimetric analyses（TGA） and fluorescence tech- niques. Complex 1, crystallized in the triclinic space group Pi, consists of one [SiW12O40]4 anion, two discrete [Zn（phen）3]^2＋ cations and five crystal water molecules. Complexes 2 and 3 have the similar configuration to complex 1, but they crystallized in the monoclinic space group C2/c. Variable-temperature magnetic susceptibilities of complexess 2 and 3 reveal antiferromagnetism and ferromagnetism, respectively.Three new Keggin polyoxometalates, [Zn（phen）3]2[SiW12O40]＇5H2O（1）, [Co（phen）3]2[SiW12O40]（2） and [Ni（phen）3]2[SiW12O40].2H2O（3）（phen=1,10＇-phenanthroline） have been hydrothermally synthesized and characterized by elemental analysis, IR, crystal X-ray diffraction, thermogravimetric analyses（TGA） and fluorescence tech- niques. Complex 1, crystallized in the triclinic space group Pi, consists of one [SiW12O40]4 anion, two discrete [Zn（phen）3]^2＋ cations and five crystal water molecules. Complexes 2 and 3 have the similar configuration to complex 1, but they crystallized in the monoclinic space group C2/c. Variable-temperature magnetic susceptibilities of complexess 2 and 3 reveal antiferromagnetism and ferromagnetism, respectively.

关 键 词：POLYOXOMETALATE PHEN Organic-inorganic compound Hydrothermal synthesis 

分 类 号：O614.33[理学—无机化学] TS745[理学—化学]