TiO_2/CuO/Cu_2O(SeO_3)光催化去除水中腐殖酸  

PHOTOCATALYTIC PROPERTIES OF TiO_2/CuO/Cu_2O(SeO_3) ON THE REMOVAL OF HOMIC ACIE IN WATER

作　　者：杨敏[1] 鲍治宇[1] 董延茂[2] 赵丹[1] 邱旻昊 

机构地区：[1]苏州科技学院环境科学与工程学院,苏州215011 [2]苏州科技学院化学与生物工程学院,苏州215009 [3]苏州市吴中区环境监测站,苏州215111

出　　处：《环境化学》2010年第6期1038-1042,共5页Environmental Chemistry

基　　金：建设部科技攻关基金资助项目(2008-K4-19);江苏省教育厅高校科研成果产业化推进项目(JHZD08-31);苏州市科技发展计划项目(SG0847);苏州科技学院师资培养科研资助;重点学科建设科研项目

摘　　要：以Cu2Se为原料,用溶胶-凝胶法(Sol-Gel)合成了TiO2/CuO/Cu2O(SeO3)光催化剂,用XRD、FTIR和EDAX等方法进行了表征.探讨了催化剂制备过程中焙烧温度对催化剂组成、晶型结构和光催化去除水中腐殖酸性能的影响.当Cu2Se/TiO2焙烧温度为450℃,焙烧2h时,Cu2Se转化为CuO和Cu2O(SeO3).室温下当TiO2/CuO/Cu2O(SeO3)催化剂投加量为1.5g·l-1,溶液pH7.0时,水中腐殖酸的去除率可达到63.6%。The TiO2/CuO/Cu2O（SeO3） photo-catalysts were prepared by sol-gel method.The photo-catalysts were characterized by X-ray diffraction（XRD）,Fourier transform infrared spectroscopy（FTIR） and SEM-EDAX,respectively.The dependence of crystal structure of TiO2 on the calcination temperature was investigated.The photo-catalytic activity of the TiO2 /CuO/Cu2 O（SeO3） on the humic acid was also studied.Results showed that CuO and Cu2O（SeO3） were produced at 450℃ calcining temperature for 2 hours.The removal rate of humic acid was about 63.6% with 1.5g·l-1 dasage of the catalyst at room temperature and pH = 7.0.

关 键 词：TIO2 CUO Cu2O(SeO3) 光催化氧化 腐殖酸 

分 类 号：X13[环境科学与工程—环境科学]