BAMO及其均聚物的合成研究进展  

Review on Synthesis of BAMO and Its Homopolymer

作　　者：王文浩[1] 周集义[1] 

机构地区：[1]黎明化工研究院,河南洛阳471001

出　　处：《含能材料》2010年第5期599-603,共5页Chinese Journal of Energetic Materials

基　　金：863项目(No.863-715-19-03-02)

摘　　要：对文献报道的制备3,3-双(叠氮甲基)氧丁环(BAMO)两条路线进行了分析比较,认为Malik等人发明的的非有机溶剂的相转移催化法,是以3,3-双(氯甲基)氧丁环(BCMO)为原料制备BAMO的较好方法;Sanderson等人提出的以三溴新戊醇(TBNPA)为原料,采用相转移催化法,经两步制备BAMO的方法,是以3,3-双(溴甲基)氧丁环(BBMO)为原料制备BAMO的较好方法。Wardle等人提出的制备BAMO均聚物(PBAMO)的方法,产品的官能度和分子量可控。BF3.THF是由BAMO制备PBAMO的较好催化剂。The two routes for synthesis of 3,3-bis（azidomethyl）oxetane （BAMO） were compared. Solvent-free process for the synthesis of BAMO from 3,3-bis （ chloromethyl ） oxetane （BCMO） by phase transfer catalysis was a good method invented by Malik et al. But Sanderson et al proposed method for the synthesis of BAMO,usingtribromoneopentylalcohol （TBNPA） as the raw materials,by the phase transfer catalysis in two steps, that is another good method. Using Wardle et al proposed method for synthesis of PBAMO, the product functionality and the molecular weight are controllable. Boron trifluoride tetrahydrofuran （BF3· THF） is a very good catalyst to prerare PBAMO from BAMO.

关 键 词：有机化学 3 3-双(叠氮甲基)氧丁环(BAMO) 3 3-双(溴甲基)氧丁环(BBMO) 均聚物 相转移催化 

分 类 号：TQ560.1[化学工程—炸药化工]