(3R,4R)-欧洲榆小蠹聚集信息素的合成  

Synthesis of (3R,4R)4Methyl3heptanol

作　　者：李焰[1] 黄锦霞[1] 马兴泉[1] 陈祖兴[1] 徐章煌[1] 

机构地区：[1]湖北大学化学与材料科学学院

出　　处：《应用化学》1999年第2期72-74,共3页Chinese Journal of Applied Chemistry

基　　金：湖北省自然科学基金

摘　　要：欧洲榆小蠹原产欧洲榆树生长区，美国、加拿大及非洲北部也有分布，其成虫及幼虫蛀食榆树皮，并能传播榆疫病，从而影响榆树生长．Ｐｅａｒｃｅ等分离出其聚集信息素并鉴定其分子结构为（—）４甲基３庚醇（１）［１］，Ｍｏｒｉ等研究结果确定出其天然产物构型为...R,4R)4Methyl3heptanol, the enatiomer of aggregation pheromone of the smaller European elm bark beetle(Scolytus Multistrialus), was stereoselectively synthesized using Nbornane2,10sultam as a chiral auxiliary. The two asymmetric carbon atoms of the target product were achieved by employing asymmetric synaldolization of Npropionylbornane2,10sultam( 3 ) with propylaldehyde. The enantiomeric excess of (3R,4R)4methyl3heptanol prepared by this route is about 943%.

关 键 词：榆小蠹 信息素 合成 欧洲榆小蠹 聚集信息素 

分 类 号：TQ453.8[化学工程—农药化工]