无溶剂中性条件下分子I_2或Fe(NO_3)_3·9H_2O/NaI原位生成的I_2催化醇与甲酸甲酰化反应(英文)  

Formylation of Alcohol with Formic Acid under Solvent-Free and Neutral Conditions Catalyzed by Free I_2 or I_2 Generated in Situ from Fe(NO_3)_3·9H_2O/NaI

作　　者：Rostami AMIN Khazaei ARDESHIR Alavi-Nik HEIDAR ALI Toodeh-Roosta ZAHRA 

机构地区：[a] Department of Chemistry [2]Faculty of Science [3]University of Kurdistan [4]Zip Cod 66177-15175 [5]Sanandaj Iran[b] Faculty of Chemistry [7]Bu-Ali Sina University [8]Zip Cod 65178-38683 [9]Hamadan [10]Iran

出　　处：《催化学报》2011年第1期60-64,共5页

基　　金：Supported by Bu-Ali Sina University and University of Kurdistan Research Councils

摘　　要：Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature.I2 generated in situ from Fe(NO3)3·9H2O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions.This gives a green and efficient reaction at room temperature,in which the use of toxic and corrosive molecular I2 is avoided.Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature.I2 generated in situ from Fe（NO3）3·9H2O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions.This gives a green and efficient reaction at room temperature,in which the use of toxic and corrosive molecular I2 is avoided.

关 键 词：alcohol formic acid FORMYLATION IODINE in situ iodine SOLVENT-FREE 

分 类 号：O643.32[理学—物理化学]