杯[4]间苯二酚芳烃类酸增殖剂的合成及性能表征  

On Synthesis of Calix[4] resorcinarene Derivatives and Their Properties as Acid Proliferation Generator

作　　者：王文广[1] 柳玲[2,3] 蒲嘉陵[1] 

机构地区：[1]印刷包装材料与技术北京市重点实验室信息记录材料研究室北京印刷学院,北京102600 [2]中国机动车辆安全鉴定检测中心 [3]北京今辰西维科安全印务有限公司,北京100176

出　　处：《北京印刷学院学报》2010年第6期23-25,共3页Journal of Beijing Institute of Graphic Communication

基　　金：印刷包装材料与技术北京市重点实验室开放课题(KF201008)

摘　　要：以间苯二酚为原料,分别与正十一醛和月桂醛,在盐酸、乙醇回流条件下进行缩合成环反应,得到中间体杯[4]间苯二酚芳烃衍生物;中间体再与对甲苯磺酰氯经过酯化反应制备了两种杯[4]间苯二酚芳烃衍生物类酸增殖剂,其结构经1HNMR、IR等分析确认,同时对其基本物性进行了研究。结果表明,两种酸增殖剂都有较高的热稳定性,在常用有机溶剂中都具有较好的溶解性。The 2 calix[4]resorcinarene derivatives as acid proliferation generator were synthesized by reactions of 4-toluenesulfonyl chloride and calix[4]resorcinarene derivatives obtained by dehydrating to form cyclic tetramers between m-dihydroxybenzene and undecanal or lauraldehyde with hydrochloric acid as catalyst and ethanol as refluxing solvent.Their structures were confirmed by 1HNMR and IR.Some physical performances have been measured.It is found that these compounds had high thermo-decomposition temperature and good solubility in common organic solvents.

关 键 词：间苯二酚芳烃衍生物 酸增殖剂 对甲苯磺酸酯 

分 类 号：O625.1[理学—有机化学]