新型小分子黏土稳定剂的合成及性能  

Synthesis and Properties of a New Type of Clay Stabilizers

作　　者：郭丽梅[1] 崔岩[1] 张丽[1] 姚培正[1] 

机构地区：[1]天津科技大学材料科学与化学工程学院,天津300457

出　　处：《天津科技大学学报》2011年第1期43-46,共4页Journal of Tianjin University of Science & Technology

摘　　要：以溴代环己烷和烷基叔胺为原料合成了一类具有全新结构的黏土稳定剂,并考察其防膨效果和长效性,通过XRD和SEM分别从微观和直观上对所研制产品防膨效果进行表征.产品A的防膨率为77.06%;冲洗11次后,膨胀率为28.70%;由XRD谱图可知其晶粒大而完整,层间距为1.309 nm.结果表明,自制产品A具有防止黏土矿物水化膨胀、控制黏土微粒分散运移等一系列优良性能.A series of new type clay stabilizers were synthesized by using cyclohexyl bromide and alkyl tertiary amine as raw materials.The anti-swelling durability of the product has been investigated.Using XRD and SEM respectively to analysis the intuitive and microscopic anti-swelling effect of the agents.The rate of anti-swelling of product A is 77.06%;after flushing 11 timest,he swell rate is 28.70%.According to X-ray Diffraction patternt,he grain is large and integratedt,he interlayer distance is 1.309,nm.It shows that product A has excellent ability to prevent the hydration swelling and dispersion of clay.

关 键 词：黏土稳定剂 防膨 阳离子 

分 类 号：TE39[石油与天然气工程—油气田开发工程] TE254.4