含脱氢松香酸骨架的吖啶染料的合成及其理化性质研究  

Synthesis and Physicochemical Property of the Novel Acridone Pigments Bearing Dehydroabietyl Skeleton

作　　者：田小艳[1] 杨达[1] 潘英明[1] 童碧海[1] 苏桂发[1] 王恒山[1] 

机构地区：[1]广西师范大学化学化工学院药用资源化学与药物分子工程重点实验室,桂林541004

出　　处：《有机化学》2011年第3期346-355,共10页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.20762001);广西林产化学品开发与应用重点实验室开放基金(No.GXFC08-05);广西新世纪十百千人才工程人选(No.2007228);广西自然科学基金创新团队(No.2010GXNSFF013001)资助项目

摘　　要：以脱氢松香酸为原料,经甲酯化、硝化、还原、关环和水解等多步合成了三个松香基吖啶酮化合物7a～7c.通过1H NMR,13C NMR,MS和IR等表征手段对产物结构进行了表征,并采用紫外-可见分光光度法对化合物的理化性质进行研究.Three novel dehydroabietyl acridone derivatives 7a～7c were synthesized through several steps such as nitration,reduction and cyclization by using dehydroabietatic acid as a starting material.The title compounds were characterized by 1H NMR,13C NMR,IR and MS techniques.The physicochemical proper-ties of compounds were investigated by UV-Vis spectrum.

关 键 词：脱氢松香酸 吖啶酮 红色素 理化性质 

分 类 号：TQ610.1[化学工程—精细化工]