Ce02／NaZSM-5分子筛降低卷烟主流烟气中烟草特有N-亚硝胺的研究  

Reducing tobacco-specific nitrosamines in cigarette mainstream smoke by CeO2/NaZSM-5 zeolite

作　　者：方智勇[1] 张悠金[1] 韩开冬[1] 徐振宇[1] 尹小斌[1] 祝玮[1] 舒俊生[2] 徐迎波[2] 丁乃红[2] 田振峰[2] 徐志强[2] 朱栋梁[2] 张尚明[2] 许宗宝[2] 

机构地区：[1]中国科学技术大学化学系,烟草与健康研究中心,合肥230026 [2]安徽中烟工业公司,合肥230088

出　　处：《中国烟草学报》2010年第B12期61-65,共5页Acta Tabacaria Sinica

基　　金：国家烟草专卖局科研项目（合同号：110200601042,降低都宝卷烟中烟草特有亚硝胺的关键技术研究和应用）

摘　　要：以NaZSM-5分子筛、Ce（N03）3·6H2O为原料通过浸渍-煅烧法制备了Ce02／NaZSM-5分子筛，利用透射电子显微镜（TEM）、X射线粉末衍射（XRD）、高分辨透射电子显微镜（HRTEM）以及热重一差热分析（TG）等技术对材料表面化学状态和体相结构进行了表征，考察了煅烧温度、Ce添加量对分子筛降低主流烟气中烟草特有N-亚硝胺的影响。结果表明：在400℃煅烧制备的CeO2／NaZSM-5分子筛按4％添加量添加到烟丝中对烟草特有N-亚硝胺降低效果较好，对主流烟气中的烟草特有N-亚硝胺总量降低率达33．6％，对NNK的降低率达25．7％。CeO2/NaZSM-5 zeolite was synthesized by soakaging-calcining method using NaZSM-5 and Ce（NO3）3·6H2O as raw materials. Effects of calcination temperature and Ce loading amount on the reduction of tobacco-specific nitrosamines in cigarette mainstream smoke was examined. The product was characterized by means of transmission electron microscopy （TEM）, powder X-ray diffraction （XRD） , high resolution transmission electron microscopy（ HRTEM）, and thermogravimetry （TG）to verify the surface chemical state and the structure of the CeO2/NaZSM-5 zeolite. Results indicated that the optimum calcinated temperature for CeO2/NaZSM-5 zeolite to reduce tobacco-specific nitrosamines was 400℃ and the optimum dosage in cigarettes was 4 %, the gross of tobacco-specific nitrosamines was reduced by 33.6 %, and the NNK was decreased by 25.7%.

关 键 词：CeO2/NaZSM-5分子筛 主流烟气 烟草特有亚硝胺 降低 

分 类 号：TS411[农业科学—烟草工业]