Cationic Micelle-catalyzed Ring-Opening Reactions of Aziridines with Thiols in Water  

作　　者：Yang, Min Yang, Qin Chen, Puqing Peng, Yiyuan 

机构地区：[1]Key Laboratory of Functional Small Organic Molecule, Ministry of Education and College of Chemistry and Chemical Engineering, Nanchang, Jiangxi 330022, China [2]Jiangxi Key Laboratory of Green Chemistry and College of Life Science, Jiangxi Normal University, Nanchang, Jiangxi 330022, China

出　　处：《Chinese Journal of Chemistry》2011年第3期499-503,共5页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （Nos. ＇20862009, 20962010）, Jiangxi Educational Committee （No. G J J10386） and the National Natural Science Foundation of Jiangxi Province （No. 2008GQH0026）.

摘　　要：An efficient and practical method is described for the ring-opening reactions of N-tosylaziridines with various thiols in water under mild conditions. Various surfactants have been evaluated to optimize the reactions. Under optimal conditions, these reactions gave rise to the corresponding β-amino sulfides in good to excellent yields.An efficient and practical method is described for the ring-opening reactions of N-tosylaziridines with various thiols in water under mild conditions. Various surfactants have been evaluated to optimize the reactions. Under optimal conditions, these reactions gave rise to the corresponding β-amino sulfides in good to excellent yields.

关 键 词：PYRIDINE-N-OXIDE ring-opening reaction N-tosylaziridine THIOL β-amino sulfide 

分 类 号：TQ423.12[化学工程] O626[理学—有机化学]