the National Natural Science Foundation of China(Grant Nos.52025031,21690071,22001004,U19B6001 and U1904212);K.C.Wong Education Foundation。
A series of dibenzhydryl-based iminopyridine-N-oxide ligands bearing a range of electron-donating or-withdrawing substituents(OMe,H;and NO_(2))and corresponding nickel pre-catalysts are prepared and characterized.The ...
the supports of the National Natural Science Foundation of China(21991101,2191100);the Key Project of Science&Technology Department of Sichuan Province(2017JZ0011)for this work。
3-Methylpyridine-N-oxide is an essential intermediate in the preparation of 2-chloro-5-methylpyridine,which can be used to synthesize nicotine insecticides such as imidacloprid and acetamiprid.The traditional method o...
Project supported by the National Natural Science Foundation of China (Nos. '20862009, 20962010), Jiangxi Educational Committee (No. G J J10386) and the National Natural Science Foundation of Jiangxi Province (No. 2008GQH0026).
An efficient and practical method is described for the ring-opening reactions of N-tosylaziridines with various thiols in water under mild conditions. Various surfactants have been evaluated to optimize the reactions....
Project supported by the National Natural Science Foundation of China (Nos. 20862009 and 20962010) and the Natural Science Foundation of Jiangxi Province (No. 2008GQH0026).
Pyridine-N-oxide serves as an efficient catalyst for the ring-opening reactions of N-tosylaziridines with various aryl thiols under mild conditions. This transformation is highly effective, which gives rise to the cor...
supported by the National Natural Science Foundation of China (No. 50872057)
Two new binary cocrystals formulated as POM·NBA 1 and POM·DNSA 2 (POM = 3-methyl-4-nitro-pyridine-N-oxide, NBA = o-nitrobenzoic acid, DNSA = 3,5-dinitrosalicylic acid) have been successfully synthesized and charac...
A three component one-pot protocol was investigated for the synthesis of methylene bis isoxazolo[4,5-b]-pyridine-N-oxides from commercially available materials.
The title complex [Mn(μ1,5-dca)2(POM)2] (C16H12MnN10O6,Mr = 495.30) has been prepared and structurally characterized. It crystallizes in triclinic,space group P1 with a = 7.4685(9),b = 7.5406(9),c = 9.8646...
A new ligand, N,N′-Bis(6-methyl-2-pyridine-N-oxide)-1,3-propane (L), and some binary lanthanide complexes (Ln=Eu^(3+), Tb^(3+)) were synthesized and characterized in detail. The composition of the binary complexes wa...
This paper describes the direct oxidation of pyridines to pyridine-N-oxides by means of 30% H2O2 in aq media in the presence of Na2WO4.2H(2)O as catalyst instead of with per-acids or 30% H2O2 in acetic acid. Good yiel...
In the screening tests of drugs for silicosis in our laboratory, we found that TT, a type of alkaloid isolated from Stephania tetrandra, could inhibit the development of experimental silicosis of rats and the synthesi...