Pyridine-N-oxide： An Efficient Organocatalyst for Ring- Opening Reactions of Aziridines with Aryl Thiols  

作　　者：Yang, Qin Yin, Zhenlan Yang, Min Peng, Yiyuan 

机构地区：[1]Jiangxi Key Laboratory of Green Chemistry, Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330027, China [2]Key Laboratory of Functional Small Organic Molecule, Ministry of Education, College of Life Science, Jiangxi Normal University, Nanchang, Jiangxi 330022, China

出　　处：《Chinese Journal of Chemistry》2011年第1期79-84,共6页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （Nos. 20862009 and 20962010） and the Natural Science Foundation of Jiangxi Province （No. 2008GQH0026）.

摘　　要：Pyridine-N-oxide serves as an efficient catalyst for the ring-opening reactions of N-tosylaziridines with various aryl thiols under mild conditions. This transformation is highly effective, which gives rise to the corresponding β-amino sulfides in good to excellent yields.Pyridine-N-oxide serves as an efficient catalyst for the ring-opening reactions of N-tosylaziridines with various aryl thiols under mild conditions. This transformation is highly effective, which gives rise to the corresponding β-amino sulfides in good to excellent yields.

关 键 词：PYRIDINE-N-OXIDE ring-opening reaction N-tosylaziridine THIOL β-amino sulfide 

分 类 号：O626[理学—有机化学] TQ174.758[理学—化学]