Unprecedented α-Octamolybdate Derivative Containing Hexad-track Cu―bpe Chains,2{[Cu(bpe)]_6[α-Mo_8O_(26)]_(3/2)}·[Cu(bpe)]_3·3H_2O  

作　　者：SHA Jing-quan LI Xin PENG Jun ZONG Xi-ming ZHANG Yu-hong YAN Hong 

机构地区：[1]Heilongjiang Provincial Key Laboratory of Biomaterials and Biological Medicine Formulation, School of Pharmacy, Jiamusi University, Jiamusi 154007, P. R. China [2]Key Laboratory of Polyoxometalate Science, Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

出　　处：《Chemical Research in Chinese Universities》2011年第2期166-169,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China(Nos.20901031 and 21071029);the Natural Science Foundation of Heilongjiang Province;China(No.B200916);the Education Ministry Key Teachers Foundation of Heilongjiang Province;China(No.1155G53);the Talent Training Fund of Jiamusi University; China(No.RC2009-034)

摘　　要：A new inorganic-organic hybrid constructed from α-octamolybdate polyoxometalates modified by hexad- track Cu―bpe chains, 2{[Cu（bpe）]6[α-Mo8O26]3/2}·[Cu（bpe）]3·3H2O[1, bpe=bis（4-pyridyl）ethylene], has been synthesized and structurally characterized. X-Ray diffraction analysis reveals that each α-octamolybdate cluster links six transition metal complex chains and the title compound has represented the highest connective number of M―N chains modified octamolybdate POMs to date. Note that there are two crystallographically unique [α-Mo8O26]n- clusters and eight unique copper sites, which play an important role in the overall architecture of hybrid compounds. Additionally, the electrochemical properties of the title compound were studied.A new inorganic-organic hybrid constructed from α-octamolybdate polyoxometalates modified by hexad- track Cu―bpe chains, 2{[Cu（bpe）]6[α-Mo8O26]3/2}·[Cu（bpe）]3·3H2O[1, bpe=bis（4-pyridyl）ethylene], has been synthesized and structurally characterized. X-Ray diffraction analysis reveals that each α-octamolybdate cluster links six transition metal complex chains and the title compound has represented the highest connective number of M―N chains modified octamolybdate POMs to date. Note that there are two crystallographically unique [α-Mo8O26]n- clusters and eight unique copper sites, which play an important role in the overall architecture of hybrid compounds. Additionally, the electrochemical properties of the title compound were studied.

关 键 词：OCTAMOLYBDATE Hydrothermal synthesis Multi-track chain Electrochemical property 

分 类 号：O641.4[理学—物理化学] TN713[理学—化学]