financially supported by Joint Fund Project of the Natural Science Foundation of Jilin Province(No.YDZJ202301ZYTS290)。
Hydrogen evolution electrocatalysts derived from metal-organic crystalline frameworks can inherit the merits of ordered and adjustable structures with high surface area.In this paper,organic-octamolybdate crystalline ...
financially supported by the National Natural Science Foundation of China (Nos.22271021,21901018 and 21971024);the Natural Science Foundation of Liaoning Province (No.2022-MS-373);Liaoning Revitalization Talents Program (No.XLYC1902011)。
The design and synthesis of catalysts for the oxidation desulfurization and production of hydrogen are extremely important for solving environmental pollution and energy shortage.Herein,a novel bifunctional [α-Mo_(8)...
supported by the Science and Technology Development Foundation of Jilin Province(201201105,201215171)
A novel organic-inorganic hybrid, Na2(Hmorph)2[MosO26]·2H2O (1, Hmorph = morpholine), has been synthesized by convenient aqueous solution method and structurally characterized by single-crystal X-ray diffraction,...
the National Natural Science Foundation of China (21171179);Natural Science Foundation of He’ nan Province (112300410291);He’ nan Educational Committee (2011B140025, 12A150028, 12A140017);Ph. D. Programs Foundation of Zhoukou Normal University
A high dimensional copper coordination polymer {[Cu2(btb)2(H2O)4( -Mo8O26)] H2O}n(1, btb = 1,4-bis(1,2,4-triazol-1-yl)butane) based on [ -Mo8O26]4 anions and flexible bis(triazole) ligands has been synthes...
supported by Financial support from the Natural Science Foundation of Shandong Province (BR2010BQ023);Shandong Provincial Education Department,and Qilu Normal University
Two new polyoxomolybdate compounds,namely(CuIIL2)2[CuⅡ(HL)2]2[Mo8O26(HL)2].(H2O)4(1) and [CuⅡ(HL)2]2[β-Mo8O26](HL)2(2)(HL=imidazole),were designed and synthesized under hydrothermal conditions.X-r...
Supported by the National Natural Science Foundation of China(Nos.20901031 and 21071029);the Natural Science Foundation of Heilongjiang Province;China(No.B200916);the Education Ministry Key Teachers Foundation of Heilongjiang Province;China(No.1155G53);the Talent Training Fund of Jiamusi University; China(No.RC2009-034)
A new inorganic-organic hybrid constructed from α-octamolybdate polyoxometalates modified by hexad- track Cu―bpe chains, 2{[Cu(bpe)]6[α-Mo8O26]3/2}·[Cu(bpe)]3·3H2O[1, bpe=bis(4-pyridyl)ethylene], has been s...
Supported by the National Natural Science Foundation of China (No 20371014 and 20671026);the Study Technological Innovation Projects Special Foundation of Harbin (2009RFXXG202)
A supramolecular compound(H2en)2[Cu(en)2(H3O)2][Mo8O28](en=ethylenediamine) was hydrothermally prepared and confirmed by elemental analysis and TG analysis.Single-crystal X-ray analysis reveals that the crysta...
supported by the National Natural Science Foundation of China (No. 20671016);Education Committee of Jilin Province "11th Five-year Plan" Natural Science Foundation (No. 2006124)
The title compound, [Ni(C8N3H7)3]4[Mo8O26]2·6H2O 1, has been synthesized from the reaction of 2-(1H-pyrazol-3-yl)-pyridine (L) with (NH4)2MoO4·2H2O and NiCl2·6H2O. Elemental analysis, IR, UV spectra and X-r...
This work was supported by the 973 Program of the MOST (001CB108906), the National Natural Science Foundation of China (90206040, 20425313, 20333070, 20521101, and 20303021), the Natural Science Foundation of Fujian Province (2005HZ01-1), and the Chinese Academy of Sciences
[{Cu(phen)(DMF)2}2(β-Mo8O26)] 1 (C36H44Cu2Mo8N8O30, Mr = 1963.39, phen =- 1,10-phenanthroline) and [Cu(phen)2]2[{Cu(phen)}2Mo8O26] 2 (C72H48Cu4Mo8N12O26, Mr = 2518.90) have been synthesized from (Bu4N...
The project was supported by the National Doctoral Research Foundation of China, Henan Innovation Project for University Prominent Research Talents, the Institute of Education of Henan Province and Natural Science Foundation of Henan Province
A hybrid compound [Mn(2,2'-bipy)3]2[β-Mo8O26]·4H2O prepared by the hydrothermal method consists of a [β-Mo8O26]^4- isopolyanion, two isolated manganese-bipyridyl units [Mn(2,2'-bipy)3]^2+ and four crystal wa...