α,α-二甲基苄醇的氯代研究  

Study on Chlorination of α,α-dimethyl Benzylalcohol

作　　者：贾云宏[1] 王立冬[1] 赵晨晨[1] 马玉梅[1] 

机构地区：[1]辽宁医学院药学院,辽宁锦州121001

出　　处：《安徽农业科学》2011年第8期4462-4463,共2页Journal of Anhui Agricultural Sciences

摘　　要：[目的]研究α,α-二甲基苄醇的氯代反应。[方法]采用不同的氯代体系进行氯代,确定氯代反应的最佳体系。[结果]在氯化亚砜-二氯甲烷体系中,氯化亚砜过量并延长反应时间,可得到理想的结果,收率为97%。[结论]氯化亚砜-二氯甲烷体系具有良好的氯代效果,反应温和且收率较高。[Objective] The purpose was to study chlorination of αα-dimethyl benzylalcohol.[Method] The chlorination was carried out in different chlorination system to ensure the optimum system of chlorination.[Result] In SOCl2-dichloromethane system,when SOCl2 was excess and reaction time was lasting,the satisfactory results would be obtained and the yield would reach 97%.[Conclusion] SOCl2-dichloromethane system had good chlorinated effectiveness,mild conditions and excellent yield.

关 键 词：氯代反应 氯化亚砜 

分 类 号：S482.3[农业科学—农药学]