钕-邻苯二胺配合物的合成、表征及性能研究  

Synthesis,Characterization and Properties of A Novel Neodymium(Ⅲ) Complex Based on o-Phenylenediamine Ligand

作　　者：苏进雄[1] 何福兰[1] 祁晓婷[1] 王娟[1] 

机构地区：[1]湖北大学化学化工学院,湖北武汉430062

出　　处：《化学与生物工程》2011年第4期36-38,共3页Chemistry & Bioengineering

基　　金：湖北省自然科学基金资助项目(2009CDB164)

摘　　要：合成了稀土钕和邻苯二胺的配合物,通过元素分析、红外光谱、紫外光谱和荧光光谱对其结构进行了表征,并对其电化学性质进行了研究,初步推测了配位反应的机理。荧光光谱分析表明,室温下配合物在543.7 nm处有较强的发射峰;在-0.4~0.4 V（vs.SCE）电势范围内,配合物具有明显的电化学活性。A novel neodymium（Ⅲ） complex based on o-phenylenediamine ligand was synthesized.And the novel complex was characterized by elemental analysis,IR,UV and fluorescence spectrum analysis.The fluorescence spectrum of the complex indicated that the novel complex had strong emission peak at 543.7 nm at room temperature.It was proved that the complex had electrochemical activity in the potential range of-0.4～0.4 V（vs.SCE） by cyclic voltammetry analysis.

关 键 词：钕(Ⅲ)配合物 邻苯二胺 荧光 电化学性质 

分 类 号：O611.3[理学—无机化学]