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作 者:王亚霄[1] 付俊伟[1] 王晶[1] 罗天骄[1] 董旭光[1] 杨院生[1]
出 处:《金属学报》2011年第4期410-416,共7页Acta Metallurgica Sinica
基 金:国家重点基础研究发展计划资助项目2007CB613705~~
摘 要:采用加热-激冷方法和OM,SEM,XRD,DSC等分析手段,研究了AZ80-Bi镁合金的凝固行为,分析了合金的凝固组织特征及其演变过程,阐明了合金的凝固序列.AZ80-2%Bi(质量分数)合金的铸态显微组织由α-Mg,β-Mg_(17)Al_(12)和Mg_3Bi_2相组成,其中Mg_3Bi_2相以片状和颗粒状两种形态存在.将2%Bi加入AZ80合金后,影响了合金的凝固序列,二元共晶转变L→α-Mg+β-Mg_(17)Al_(12)(437℃)被三元共晶转变L→α-Mg+β-Mg_(17)Al_(12)+Mg_3Bi_2(435℃)代替.2%Bi的加入使AZ80合金的初晶形核温度由568.8℃降低至562.6℃,共晶平台温度由424.2℃降到421.1℃.The solidification behavior and as-cast microstructure in AZ80-Bi magnesium alloy were analysed by OM,SEM,XRD and DSC.Meanwhile,the evolution of the solidification microstructure of AZ80-2%Bi alloy was studied by heating-quenching experiments.The results show that the as-cast microstructure of AZ80-2%Bi consists of primaryα-Mg matrix,divorced eutecticβ-Mg_(17)Al_(12) phase and Mg_3Bi_2 phase.The Mg_3Bi_2 phase exists in the flake-like and granule-like morphologies. With 2.0%Bi addition,the solidification procedure of AZ80 magnesium alloy is changed.The ternary eutectic transformation L→α-Mg+β-Mg_(17)Al_(12)+Mg_3Bi_2(at 435℃) takes place during solidification of AZ80-2%Bi alloy instead of the binary eutectic transformation L→α-Mg+β-Mg_(17)Al_(12)(at 437℃) in AZ80 alloy.Comparing with AZ80 alloy,the nucleating temperature of primaryα-Mg in AZ80- 2%Bi alloy is decreased from 568.8℃to 562.6℃,and the eutectic temperature is also decreased from 424.2℃to 421.1℃.
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