D-酒石酸丙烯酯的合成研究  

The Study on the Synthesis of Allyl D-tartrate

作　　者：王树民[1,2] 周伟良[2] 赵云[3] 段涛[3] 

机构地区：[1]西南科技大学分析测试中心,四川绵阳621010 [2]南京理工大学化工学院,江苏南京210094 [3]西南科技大学极端条件物质特性实验室,四川绵阳621010

出　　处：《广州化工》2011年第13期52-53,69,共3页GuangZhou Chemical Industry

基　　金：四川省教育厅基金(09ZC009);西南科技大学博士基金(07ZX7130)

摘　　要：以D-酒石酸和丙烯醇为原料合成了酒石酸丙烯酯。考察研究了催化剂用量、反应温度和时间等因素对产物产率的影响。结果表明:酒石酸和丙烯醇摩尔比为1.0∶2.5,1.0%对甲苯磺酸,1.0%对苯二酚,反应温度80℃,反应时间为8 h,酒石酸丙烯酯的产率达到96.6%;并对产品结构进行了红外光谱表征。Allyl D-tartrate was prepared by refluxing D-tartrate and allyl alcohol.The parameters of the esterification that forms allyl D-tartrate,such as the effect of the mole ratio of D-tartrate and allyl alcohol,the content of p-toluenesulfonic acid,the reaction temperature and time on yield of allyl D-tartrate were investigated.The optimum conditions were the mole ratio of D-tartrate and allyl alcohol 1.0：2.5 with 1.0% p-methy benzene sulfonic acid and 1.0% hydroquinone at 80 ℃ for 8 h.The yield of product reached more than 96.6%,and its structure was characterized by FTIR.

关 键 词：D-酒石酸 丙烯醇 D-酒石酸丙烯酯 酯化反应 

分 类 号：TQ921.7[轻工技术与工程—发酵工程]