一类重要含能材料:5取-代四唑含能金属配合物  

An Important Energetic Material:5-Substituted Tetrazole Energetic Metal Complexes

作　　者：舒远杰[1] 李华荣[1] 高晓敏[1] 殷明[1] 熊鹰[1] 李寅川[2] 

机构地区：[1]中国工程物理研究院化工材料研究所,四川绵阳621900 [2]西南科技大学材料科学与工程学院,四川绵阳621010

出　　处：《含能材料》2011年第5期588-596,共9页Chinese Journal of Energetic Materials

基　　金：中国工程物理研究院"双百人才工程"基金(ZX03010);中俄国际合作项目(No.10610194 No.11011120241/A0401)

摘　　要：分类综述了5-取代四唑金属含能配合物(TEMCs)的合成及研究进展。目前,国内外关于TEMCs的研究不多,其中以5-氰基四唑(CT)、5-硝基四唑(NT)、5-氨基四唑(AT)为配体的TEMCs因其优越的性能和突出的特点,成为含能材料领域研究的重要方向。经过调研、分析,得出如下结论:①TEMCs的合成步骤较少、反应条件温和、易于操作和控制、产率高,且环境友好,但对其结构与性能的研究较困难,特别是对其固态摩尔生成焓的探究没有文献报道;②可通过改变外阳离子或中心金属离子、调控配合物分子中配体数目、调控合成过程等方式寻找性能优良的TEMCs;③通过有目的的设计和选择合适的配体与金属离子以及控制反应条件等因素来系统研究配合物的结构与性能,对指导实验研究具有重要意义。The recent domestic and international studies on tetrazole energetic metal complexes（TEMCs） were classified and reviewed.Some synthesis and research trends of the TEMCs were introduced.5-Cyanotetrazole（CT）,5-nitrotetrazolium（NT） and 5-aminotetrazole（AT） are the three most important ligands,which have attracted more and more attention due to their excellent performance and distinctive structure characteristics.Our recommendations are as follows：（1） The synthesis processes of TEMCs have such advantages as less separation steps,mild reaction condition,easy operation,fine controllability,high yield and less pollution.However,the structure and properties studies are still difficult.And the inquiry into the solid-state molar enthalpy of formation has not been reported in the literatures.（2） Altering the central metal ions or the outside cations,changing the number of ligands and modifying preparation methods are all possible ways to search TEMCs that could meet our requirements.（3） Systematic study on the structure and properties of these complexes should be carried out through designing and selecting proper ligands and metal ions,and meanwhile,controlling all the factors such as reaction conditions,which might be of important significance to the experimental study.

关 键 词：有机化学 含能材料 5取-代四唑金属含能配合物(TEMCs) 四唑配体 综述 

分 类 号：O641.4[理学—物理化学]