Synthesis of the Acetate of a New Phenolic Glycoside,Anacardoside,from Semecarpus anacardium and its Diastereomer  

作　　者：Yu Lan WANG Cheng He ZHOU Meng Shen CAI (Institute of Chemical Metallurgy, Chinese Academy of Sciences, Bejing 100080)( School of Pharmaceutical Sciences, Beijing Medical University, Beijing 100083) 

出　　处：《Chinese Chemical Letters》1998年第6期533-536,共4页中国化学快报（英文版）

摘　　要：the acetate of a novel phenolic glycoside, 1-O-beta-D-glucopyranosyl-( 1-->6)-beta-D-glucopyranosyloxy-3-hydroxy-5-methylbenzene anacardoside, from the fruits of Semecarpus anacardium, and its diastereomer were first synthesized using Koenigs-Knorr method from D-glucose through six steps with total yields 33% and 16% respectively.the acetate of a novel phenolic glycoside, 1-O-beta-D-glucopyranosyl-( 1-->6)-beta-D-glucopyranosyloxy-3-hydroxy-5-methylbenzene anacardoside, from the fruits of Semecarpus anacardium, and its diastereomer were first synthesized using Koenigs-Knorr method from D-glucose through six steps with total yields 33% and 16% respectively.

关 键 词：acetate of anacardoside DIASTEREOMER SYNTHESIS phenolic glycoside 

分 类 号：O625[理学—有机化学]