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This work was supported by the China NSF(Nos.31670087 and U1706206);the Natural Key Research and Development Program of China(No.2019YFC0312500);the Key Special Project for Introduced Talents Team of Southern Marine Science and Engi-neering Guangdong Laboratory(Guangzhou,No.GML2019ZD0406);the Guangdong NSF(No.2016A030312014);the Guangdong Local Innovation Team Program(No.2019BT02Y262);the Pearl River S&T Nova Program of Guangzhou No.201806010109);the CAS(No.XDA13020302-2);the Guangdong Provincial-Level Special Funds for Promoting High-quality Economic Development(No.2020032).
Main observation and conclusion The enzyme AbyU catalyses a Diels-Alder(DA)reaction during abyssomicin C biosynthesis.In this study,AbyU is shown to convert the native substrate of another Diels-Alderase(DAase),AbmU,t...
Morpholine fungcides have certain antibacterial side effect, dodemorph being the most active among them. The diequatorial (cis-)?form of dodemorph expressed higher antibacterial activity than the axial-equatorial (tra...
Supported by the National Natural Science Foundation of China(No.21302141) and the Key Projects of Tianjin Science and Technology Support Plan,China(No.10ZCKFSH01300).
A facile 7-step procedure for the synthesis of enantiomerically pure 1-(5-bromo-2-chlorophenyl)-1-(4-ethoxyphenyl)ethanes[(R)-2 and(S)-2] that started from (5-bromo-2-chlorophenyl)(4-ethoxyphenyl)methanone...
financially supported by the National Natural Science Foundation of China(Nos.20832008 and 21002004)
Linear diribonucleoside phosphotriester is an important intermediate for synthesizing biologically important compounds, such as cyclic bis(3'-5') diguanylic acid (c-di-GMP) and its analogues. Atropisomerism of d...
A facile method for the synthesis of a new series of R,R-2-(4-(2-(4-(5-chloro-3-halopyridin-2-yloxy)-phenoxy)-propionyloxy)-phenoxy) -propionic acid ester derivatives containing a halo-substituted pyridine car...
Asymmetric 6-substituted-2-methoxy-4-(2,4-dichlorophenyl)-4H-1,3,2-benzodioxaphosphorin a-sulfides were prepared from intramolecular cyclization. The diastereomers were separated by column chromatography and fractiona...
the acetate of a novel phenolic glycoside, 1-O-beta-D-glucopyranosyl-( 1-->6)-beta-D-glucopyranosyloxy-3-hydroxy-5-methylbenzene anacardoside, from the fruits of Semecarpus anacardium, and its diastereomer were first ...