Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles  

作　　者：Jing Song YOU Xiao Qi YU Xiao Ling ZHANG and Ru Gang XIE(Department of Chemistry, Sichuan University, Chengdu 610064) 

出　　处：《Chinese Chemical Letters》1998年第4期335-337,共3页中国化学快报（英文版）

摘　　要：A series of chiral lipophilic Cu(Ⅱ) complexes were investigated as catalysts for the enantioselective hydrolysis of R(S)-p-nitrophenyl N-dodecanoyl-phenylalaninate in micelles. The highest enantioselectivity (kR/ks=7. 81) was observed in a mixed micellar system composed of 1-Cu(Ⅱ) and Brij35.A series of chiral lipophilic Cu(Ⅱ) complexes were investigated as catalysts for the enantioselective hydrolysis of R(S)-p-nitrophenyl N-dodecanoyl-phenylalaninate in micelles. The highest enantioselectivity (kR/ks=7. 81) was observed in a mixed micellar system composed of 1-Cu(Ⅱ) and Brij35.

关 键 词：MICELLE chiral metallomicelle enantioselective hydrolysis 

分 类 号：O621[理学—有机化学]