SOLID-LIQUID PHASE TRANSFER CATALYTIC SYN THESIS Ⅸ: THE SYNTHESIS OF α-AMINO ACIDS VIA ALICYLATION OF ALDIMINE UNDER MICROWAVE IRRADIATION,  

作　　者：Run Hua DENG Ai Qiao MI Yao Zhong JIANG Chengdu Institute of Organic Chemistry, Academia Sinica, Chengdu 610015 

出　　处：《Chinese Chemical Letters》1993年第5期381-384,共4页中国化学快报（英文版）

摘　　要： The rapid alkylation of methyl N-benzylidene glycinate with halides under microwave irradiation using solid-liquid phase transfer condition without solvent has been achieved wilhin only one minute. After hydrolysis of alkylated products the corresponding α-amino acids were obtained in overall yield 43.6～62.5%.The rapid alkylation of methyl N-benzylidene glycinate with halides under microwave irradiation using solid-liquid phase transfer condition without solvent has been achieved wilhin only one minute. After hydrolysis of alkylated products the corresponding α-amino acids were obtained in overall yield 43.6～62.5%.

关 键 词：SYN THE SYNTHESIS OF AMINO ACIDS VIA ALICYLATION OF ALDIMINE UNDER MICROWAVE IRRADIATION SOLID-LIQUID PHASE TRANSFER CATALYTIC SYN THESIS VIA 

分 类 号：O6[理学—化学]