Waugh结构(NH_4)_6[MnMo_9O_(32)]·8H_2O催化合成乙酸异戊酯  

Synthesis of Isoamyl Acetate Catalyzed by (NH_4)_6[MnMo_9O_(32)]·8H_2O with Waugh Structure

作　　者：袁华[1] 王立霞[1] 徐美[1] 刘伟[1] 杨凤珍[1] 刘树恒[1] 

机构地区：[1]沧州师范学院化学与环境科学系,河北沧州061001

出　　处：《河北师范大学学报（自然科学版）》2011年第6期602-604,共3页Journal of Hebei Normal University：Natural Science

基　　金：河北省高等学校自然科学研究项目(Z2010107)

摘　　要：以Waugh结构钼锰杂多酸盐作为催化剂对乙酸异戊酯的合成进行了催化研究.确定了最佳反应条件:醇酸摩尔比为1.646∶1,酸化催化剂用量为0.2 g,带水剂为3 mL甲苯,反应时间63 min左右,选择性100%,转化率达82.70%.The synthesis of isoamyl acetate with ammonium 9-molybdomanganesate as catalyst was studied.The optimum reaction conditions were obtained as follows：isoamyl alcohol to acetic acidmolar rat=1.646,m（acidulate catalyst）=0.2 g,V（water-carrying reagent toluene）=3 mL,reaction time was about 63 minutes.Selectivity was 100 % and conversion rate was 82.70 %.

关 键 词：WAUGH结构 钼锰杂多酸盐 催化剂 乙酸异戊酯 

分 类 号：O614[理学—无机化学]