牛磺酸对B-Z化学振荡体系的影响及其分析检测  被引量:2

Effect of Taurine for the B-Z Oscillating Chemical Reaction and Its Analytical Determination

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作  者:王莉 郝文龙[2] 张庆富[2] 孙德志[2] 

机构地区:[1]聊城市环境保护局,山东聊城252000 [2]山东省化学储能与新型电池技术重点实验室聊城大学化学化工学院,山东聊城252059

出  处:《聊城大学学报(自然科学版)》2012年第1期52-56,共5页Journal of Liaocheng University:Natural Science Edition

基  金:聊城大学科研基金(31805)

摘  要:在连续搅拌反应器(CSTR)中,研究了牛磺酸对封闭体系中的B-Z振荡体系的影响.结果表明:牛磺酸的浓度在4×10-6-4×10-1 mol/L范围内振幅变化值(ΔE)与牛磺酸浓度(c)的关系符合方程:ΔE=14.062c0.126,R2=0.990 1,最低检测限达10-6 mol/L.A new and convenient method was presented for the determination of taurine,which was based upon sequential perturbation of B-Z oscillating system with different amounts of taurine in a continuous-flow stirred tank reactor(CSTR).The results showed that the relationship between change in oscillating amplitude(ΔE) and taurine concentration(c) was in accordance with the equation ΔE = 14.062 c0.126 in the range of 4×10-6 to 4×10-1 mol/L,with the regression coefficient of 0.990 1.The lowest detection limit was 10-6 mol/L.On this basis,the method for the determination of taurine was established.

关 键 词:B-Z化学振荡 牛磺酸 诱导期 振荡周期 

分 类 号:O643[理学—物理化学]

 

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