脂肪酸甲酯型含氮硼酸酯的合成及摩擦学性能研究  

SYNTHESIS AND TRIBOLOGICAL BEHAVIOR OF A NITROGEN-CONTAINING BORIC ACID ESTER FROM FATTY ACID METHYL ESTER

作　　者：李为民[1] 任朋飞[1] 段伟娜[1] 

机构地区：[1]常州大学石油化工学院,江苏常州213164

出　　处：《石油炼制与化工》2012年第6期71-75,共5页Petroleum Processing and Petrochemicals

基　　金：江苏省科技厅国际合作项目(BZ2010013);江苏省科技厅工程技术中心建设项目(BM2010095;BM2010132)

摘　　要：以脂肪酸甲酯为原料合成一种新型含氮硼酸酯添加剂。通过红外光谱仪对所合成添加剂进行表征,采用四球摩擦试验仪考察其在不同基础油中的摩擦学性能,同时考察摩擦时间、载荷对菜籽油润滑下钢球磨斑直径(WSD)的影响,并用扫描电子显微镜(SEM)和能谱仪(EDS)分析含氮硼酸酯添加剂对钢球摩擦表面膜的组成和化学状态的影响。结果表明:含氮硼酸酯添加剂具有良好的极压抗磨效果。在钢球磨损表面发现含有硼元素,表明在摩擦过程中,通过物理吸附和化学反应在摩擦表面生成了含硼的润滑膜,起到了极压抗磨的作用。A novel nitrogen-containing boric acid ester was synthesized from fatty acid methyl ester to be used as lubricant additive.The synthesized additive was characterized by FT-IR technique and its tribological performance in various base oils,e.g.the effect of friction time and load on PB value and wear scar diameter（WSD）,were investigated using a four-ball tester.The morphologies of the worn scars were analyzed by means of scanning electron microscopy and energy dispersive X-ray spectroscopy to study the effect of said novel additive on the compositions and chemical states of the friction surface film.Results showed that this nitrogen-containing boric acid ester additive exhibited excellent extreme pressure anti-wear performance.Boron was detected from the worn surface of tested steel ball,which indicated that a lubricating film containing boron was formed on the friction surface by physical adsorption and chemical reaction,resulting in an enhancement of extreme pressure anti-wear function.

关 键 词：菜籽油 生物柴油 脂肪酸甲酯 含氮硼酸酯 摩擦学性能 

分 类 号：TE624.82[石油与天然气工程—油气加工工程]