肉桂酸环己酯的催化合成  

CATALYTIC SYNTHESIS METHOD OF CYCLOHEXYL CINNAMATE

作　　者：唐晓红[1] 韩春亮[1] 李保军[2] 李成未[1] 

机构地区：[1]河南教育学院化学系,河南郑州450046 [2]郑州大学化学系,河南郑州450001

出　　处：《河南工业大学学报（自然科学版）》2012年第2期66-69,共4页Journal of Henan University of Technology：Natural Science Edition

基　　金：河南省科技攻关重点项目(112102310424)

摘　　要：采用中孔分子筛MCM-41为催化剂,用环己醇和肉桂酸为原料合成了肉桂酸环己酯.考察了催化剂用量、反应物物质的量比、反应温度和反应时间对肉桂酸转化率的影响.通过试验得出该反应最佳的合成条件是:肉桂酸和环己醇的物质的量配比为1∶4,催化剂的量为肉桂酸质量的2.5%,反应时间为3 h,反应在剧烈回流温度下进行.在此条件下,肉桂酸的转化率可达89.1%,纯度大于99.5%.反应条件温和,操作简单,产物提纯容易,具有工业化应用前景.In this paper,we synthesized cyclohexyl cinnamate from cinnamate and cyclohexanol by using mesoporous molecular sieves MCM-41 as catalyst for the first time, and studied the effects of catalyst amount, molar ratio of reactants, reaction temperature and reaction time on the conversion ratio of cyclohexyl cinnamate. The optimum conditions were as follows： the molar ratio of cinnamate to cyclohexanol 1：4 ,the catalyst amount 2.5% the weight of cinnamate, and reaction time 3 hours, and the reaction was carried out at a violent refluxing temperature. Under the optimum conditions, the conversion purity was larger than 99.5%. rate of cyclohexyl cinnamate reached 89.1%, and the

关 键 词：肉桂酸环己酯 中孔分子筛 催化剂 

分 类 号：TS201.2[轻工技术与工程—食品科学]