不溶性淀粉黄原酸酯合成中交联淀粉制备工艺的优化  

Optimization of Crosslinking Starch Used in the Synthesis of Insoluble Starch Xanthate

作　　者：张竹玲[1] 何川[1] 胡荣荣[1] 宋婷[1] 胡叶莉[1] 韦晓燕[1] 孙萍[2] 谭军[2] 

机构地区：[1]嘉兴学院南湖学院,浙江嘉兴314001 [2]嘉兴学院生物与化学工程学院,浙江嘉兴314001

出　　处：《嘉兴学院学报》2012年第3期59-62,共4页Journal of Jiaxing University

基　　金：浙江省分析测试科技计划项目(2009F0007);嘉兴市科技计划项目(2011AY1049);嘉兴学院重点SRT项目(851711021)

摘　　要：以玉米淀粉为原料,研究交联淀粉的合成及在不溶性淀粉黄原酸酯中的应用.采用环氧氯丙烷作交联剂,氢氧化钾提供强碱性条件下,考察交联剂的投加量、氢氧化钾的用量、反应时间、温度等对交联反应的影响.通过正交试验得出最佳交联反应条件为:质量浓度25%的KOH溶液8mL,交联剂环氧氯丙烷用量1.5mL,反应时间14h,由此制备的不溶性淀粉黄原酸酯对模拟废水中Cu2+的去除率为99.94%.Using corn starch as raw material, the synthesis of crosslinking starch and its applications in the final product -- insoluble starch xanthate is researched. The dosage of crosslinking agent which is epichlorohydrin （ECH）, the amount of potassium hydroxide, reaction time and temperature for the crosslinking reaction are discussed. The optimum synthesis conditions in the crosslink reaction obtained by the orthogonal experiments are： potassium hydroxide （ 25wt %） 8 mE, ECH 1.5 mL, reaction time 14 h. Under the conditions, the removal rate of copper of ISX is 99.94 %.

关 键 词：交联淀粉 不溶性淀粉黄原酸酯 水处理 

分 类 号：X703.1[环境科学与工程—环境工程]